Fixatives in Perfumes and Fragrances
Definition of Fixatives
Fixatives are compounds or materials that slow down the evaporation rate of volatile compounds in perfume or fragrance compositions.
Fixatives, also known as fixers, can be grouped into four categories [1]:
(i) True fixatives
Materials that slow down the evaporation of other perfume components through adsorption due to their high molecular structure, such as benzoin.
(ii) Arbitrary fixatives
Odorous compounds that impart a specific note to the perfume throughout all stages of evaporation of other fragrance materials in the composition, like oakmoss.
(iii) Exalting fixatives
Act as odor carriers, enhancing, reinforcing, or carrying the vapors of other perfume materials in the composition, such as musk.
(iv) So-called fixatives
Odorless crystals or viscous liquids with high-boiling points, which help increasing the overall boiling point of the perfume composition, for example, amyris oil.
Many perfumes or fragrances are used in various products such as leave-on skin products, colognes, personal perfumes, anti-perspirant deodorants, and hair colognes. However, the volatile compounds tend to lose their character rapidly, especially the top and middle notes. The use of fixatives can extend the life of these fragrances and preserve their initial character and intensity. Additionally, good fixatives should not alter the aesthetic characteristics of the product [2].
The term "fixatives" refers to agents capable of influencing the fragrance profile by affecting the rate of fragrance evaporation. They can lower the vapor pressure of fragrance materials and increase their adherence to the substrate, ensuring a longer-lasting impression of the fragrance [3]. Typically, fixatives constitute the base notes in perfumes and are used at concentrations of 3-5%.
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